A box contains 0.90 g of liquid water in equilibrium with water vapour at 27$$^\circ$$C. The equilibrium vapour pressure of water at 27$$^\circ$$C is 32.0 Torr. When the volume of the box is increased, some of the liquid water evaporates to maintain the equilibrium pressure. If all the liquid water evaporates, then the volume of the box must be __________ litre. [nearest integer]

(Given : R = 0.082 L atm K^{$$-$$1} mol^{$$-$$1})

(Ignore the volume of the liquid water and assume water vapours behave as an ideal gas.)

2NOCl(g) $$\rightleftharpoons$$ 2NO(g) + Cl_{2}(g)

In an experiment, 2.0 moles of NOCl was placed in a one-litre flask and the concentration of NO after equilibrium established, was found to be 0.4 mol/L. The equilibrium constant at 30$$^\circ$$C is ______________ $$\times$$ 10^{$$-$$4}.

40% of HI undergoes decomposition to H_{2} and I_{2} at 300 K. $$\Delta$$G$$^\Theta $$ for this decomposition reaction at one atmosphere pressure is __________ J mol^{$$-$$1}. [nearest integer]

(Use R = 8.31 J K^{$$-$$1} mol^{$$-$$1} ; log 2 = 0.3010, ln 10 = 2.3, log 3 = 0.477)

The standard free energy change ($$\Delta$$G$$^\circ$$) for 50% dissociation of N_{2}O_{4} into NO_{2} at 27$$^\circ$$C and 1 atm pressure is $$-$$ x J mol^{$$-$$1}. The value of x is ___________. (Nearest Integer)

[Given : R = 8.31 J K^{$$-$$1} mol^{$$-$$1}, log 1.33 = 0.1239 ln 10 = 2.3]