Number of paramagnetic complexes among the following is $\_\_\_\_$ .

$$ \begin{aligned} & {\left[\mathrm{MnBr}_4\right]^{2-},\left[\mathrm{NiCl}_4\right]^{2-},\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-},\left[\mathrm{Ni}(\mathrm{CO})_4\right],\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-},\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Ti}(\mathrm{CN})_6\right]^{3-},} \\ & {\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}} \end{aligned} $$

An excess of $\mathrm{AgNO}_3$ is added to 100 mL of a 0.05 M solution of tetraaquadichloridochromium (III) chloride. The number of moles of AgCl precipitated will be $\_\_\_\_$ $\times 10^{-3}$.

(Nearest integer)

The total number of unpaired electrons present in the $d^3, d^4$ (low spin) $d^5$ (high spin), $\mathrm{d}^6$ (high spin) and $\mathrm{d}^7$ (low spin) octahedral complex systems is $\_\_\_\_$ .

5.33 g of CrCl₃·6H₂O, which is a 1 : 3 electrolyte, is dissolved in water and is passed through a cation exchanger. The chloride ions in the eluted solution, on treatment with AgNO₃ results in 8.61 g of AgCl. The ratio of moles of complex reacted and moles of AgCl formed is ________ × 10^-2. (Nearest integer)

[Molar mass in g mol^–1 Cr : 52, Ag : 108, Cl : 35.5, H : 1, O : 16]