The overall stability constant of the complex ion [Cu(NH₃)₄]²⁺ is 2.1 $$\times$$ 10¹³. The overall dissociations constant is y $$\times$$ 10^$$-$$14. Then y is __________. (Nearest integer)

The reaction rate for the reaction

[PtCl₄]^2$$-$$ + H₂O $$\rightleftharpoons$$ [Pt(H₂O)Cl₃]^$$-$$ + Cl^$$-$$

was measured as a function of concentrations of different species. It was observed that $${{ - d\left[ {{{\left[ {PtC{l_4}} \right]}^{2 - }}} \right]} \over {dt}} = 4.8 \times {10^{ - 5}}\left[ {{{\left[ {PtC{l_4}} \right]}^{2 - }}} \right] - 2.4 \times {10^{ - 3}}\left[ {{{\left[ {Pt({H_2}O)C{l_3}} \right]}^ - }} \right]\left[ {C{l^ - }} \right]$$.

where square brackets are used to denote molar concentrations. The equilibrium constant K_c = ____________ . (Nearest integer)

The following data was obtained for chemical reaction given below at 975 K.

2NO_(g) + 2H_2(g) $$\to$$ N_2(g) + 2H₂O_(g)



The order of the reaction with respect to NO is ___________. [Integer answer]

For the first order reaction A $$\to$$ 2B, 1 mole of reactant A gives 0.2 moles of B after 100 minutes. The half life of the reaction is __________ min. (Round off to the nearest integer).

[Use : ln 2 = 0.69, ln 10 = 2.3]

Properties of logarithms : ln x^y = y ln x;

$$\ln \left( {{x \over y}} \right) = \ln x - \ln y$$

(Round off to the nearest integer)