1
JEE Main 2025 (Online) 4th April Evening Shift
Numerical
+4
-1
Change Language

A metal complex with a formula $\mathrm{MCl}_4 \cdot 3 \mathrm{NH}_3$ is involved in $\mathrm{sp}^3 \mathrm{~d}^2$ hybridisation. It upon reaction with excess of $\mathrm{AgNO}_3$ solution gives ' $x$ ' moles of AgCl . Consider ' $x$ ' is equal to the number of lone pairs of electron present in central atom of $\mathrm{BrF}_5$. Then the number of geometrical isomers exhibited by the complex is _________.

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2
JEE Main 2025 (Online) 3rd April Morning Shift
Numerical
+4
-1
Change Language

The number of optical isomers exhibited by the iron complex $(\mathrm{A})$ obtained from the following reaction is___________.

$$ \mathrm{FeCl}_3+\mathrm{KOH}+\mathrm{H}_2 \mathrm{C}_2 \mathrm{O}_4 \rightarrow \mathrm{~A} $$

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3
JEE Main 2025 (Online) 2nd April Evening Shift
Numerical
+4
-1
Change Language

The spin-only magnetic moment value of $\mathrm{M}^{\mathrm{n}+}$ ion formed among $\mathrm{Ni}, \mathrm{Zn}, \mathrm{Mn}$ and Cu that has the least enthalpy of atomisation is_________ . (in nearest integer) Here n is equal to the number of diamagnetic complexes among $\mathrm{K}_2\left[\mathrm{NiCl}_4\right],\left[\mathrm{Zn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_2$, $\mathrm{K}_3\left[\mathrm{Mn}(\mathrm{CN})_6\right]$ and $\left[\mathrm{Cu}\left(\mathrm{PPh}_3\right)_3 \mathrm{I}\right]$

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4
JEE Main 2025 (Online) 2nd April Morning Shift
Numerical
+4
-1
Change Language

A transition metal (M) among $\mathrm{Mn}, \mathrm{Cr}, \mathrm{Co}$ and Fe has the highest standard electrode potential $\left(\mathrm{M}^{3+} / \mathrm{M}^{2+}\right)$. It forms a metal complex of the type $\left[\mathrm{M}(\mathrm{CN})_6\right]^{4-}$. The number of electrons present in the $\mathrm{e}_{\mathrm{g}}$ orbital of the complex is ___________.

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