An excess of $\mathrm{AgNO}_3$ is added to 100 mL of a 0.05 M solution of tetraaquadichloridochromium (III) chloride. The number of moles of AgCl precipitated will be $\_\_\_\_$ $\times 10^{-3}$.
(Nearest integer)
The total number of unpaired electrons present in the $d^3, d^4$ (low spin) $d^5$ (high spin), $\mathrm{d}^6$ (high spin) and $\mathrm{d}^7$ (low spin) octahedral complex systems is $\_\_\_\_$ .
5.33 g of CrCl3·6H2O, which is a 1 : 3 electrolyte, is dissolved in water and is passed through a cation exchanger. The chloride ions in the eluted solution, on treatment with AgNO3 results in 8.61 g of AgCl. The ratio of moles of complex reacted and moles of AgCl formed is ________ × 10-2. (Nearest integer)
[Molar mass in g mol–1 Cr : 52, Ag : 108, Cl : 35.5, H : 1, O : 16]
The number of isoelectronic species among $Sc^{3+}, Cr^{2+}, Mn^{3+}, Co^{3+}$ and $Fe^{3+}$ is ‘n’. If ‘n’ moles of AgCl is formed during the reaction of complex with formula $CoCl_3(en)_2NH_3$ with excess of $AgNO_3$ solution, then the number of electrons present in the $t_{2g}$ orbital of the complex is ________.
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