5.33 g of CrCl₃·6H₂O, which is a 1 : 3 electrolyte, is dissolved in water and is passed through a cation exchanger. The chloride ions in the eluted solution, on treatment with AgNO₃ results in 8.61 g of AgCl. The ratio of moles of complex reacted and moles of AgCl formed is ________ × 10^-2. (Nearest integer)

[Molar mass in g mol^–1 Cr : 52, Ag : 108, Cl : 35.5, H : 1, O : 16]

The number of isoelectronic species among $Sc^{3+}, Cr^{2+}, Mn^{3+}, Co^{3+}$ and $Fe^{3+}$ is ‘n’. If ‘n’ moles of AgCl is formed during the reaction of complex with formula $CoCl_3(en)_2NH_3$ with excess of $AgNO_3$ solution, then the number of electrons present in the $t_{2g}$ orbital of the complex is ________.

X is the number of geometrical isomers exhibited by $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)\left(\mathrm{H}_2 \mathrm{O}\right) \mathrm{BrCl}\right]$.

Y is the number of optically inactive isomer(s) exhibited by $\left[\mathrm{CrCl}_2(\mathrm{ox})_2\right]^{3-}$

Z is the number of geometrical isomers exhibited by $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]$.

The value of $\mathrm{X}+\mathrm{Y}+\mathrm{Z}$ is $\_\_\_\_$ .

A chromium complex with a formula $\mathrm{CrCl}_3 \cdot 6 \mathrm{H}_2 \mathrm{O}$ has a spin only magnetic moment value of 3.87 BM and its solution conductivity corresponds to $1: 2$ electrolyte. 2.75 g of the complex solution was initially passed through a cation exchanger. The solution obtained after the process was reacted with excess of $\mathrm{AgNO}_3$. The amount of AgCl formed in the above process is $\_\_\_\_$ g. (Nearest integer)

[Given: Molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{Cr}: 52 ; \mathrm{Cl}: 35.5, \mathrm{Ag}: 108, \mathrm{O}: 16, \mathrm{H}: 1$ ]