A $$100 \mathrm{~mL}$$ solution of $$\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{MgBr}$$ on treatment with methanol produces $$2.24 \mathrm{~mL}$$ of a gas at STP. The weight of gas produced is _____________ mg. [nearest integer]

Chlorophyll extracted from the crushed green leaves was dissolved in water to make $$2 \mathrm{~L}$$ solution of Mg of concentration $$48\, \mathrm{ppm}$$. The number of atoms of $$\mathrm{Mg}$$ in this solution is $$x \times 10^{20}$$ atoms. The value of $$x$$ is ___________. (Nearest Integer)

(Given : Atomic mass of $$\mathrm{Mg}$$ is $$24 \mathrm{~g} \mathrm{~mol}^{-1} ; \mathrm{N}_{\mathrm{A}}=6.02 \times 10^{23} \mathrm{~mol}^{-1}$$ )

When 800 mL of 0.5 M nitric acid is heated in a beaker, its volume is reduced to half and 11.5 g of nitric acid is evaporated. The molarity of the remaining nitric acid solution is x $$\times$$ 10^$$-$$2 M. (Nearest integer)

(Molar mass of nitric acid is 63 g mol^$$-$$1)

56.0 L of nitrogen gas is mixed with excess hydrogen gas and it is found that 20 L of ammonia gas is produced. The volume of unused nitrogen gas is found to be _________ L.