At 518^oC the rate of decomposition of a sample of gaseous acetaldehyde initially at a pressure of 363 Torr, was 1.00 Torr s^–1 when 5% had reacted and 0.5 Torr s^–1 when 33% had reacted. The order of the reaction is

For a first order reaction, A $$ \to $$ P, t_1/2 (half-life) is 10 days The time required for $${1 \over 4}$$^th conversion of A (in days) is : (ln 2 = 0.693,    ln 3 = 1.1)

N₂O₅ decomposes to NO₂ and O₂ and follows first order kinetics. After 50 minutes, the pressure inside the vessel increases from 50 mmHg to 87.5 mmHg. The pressure of the gaseous mixture after 100 minute at constant temperature will be :

The rate of a reaction quadruples when the temperature changes from 300 to 310 K. The activation energy of this reaction is :

(Assume activation energy and preexponential factor are independent of temperature; ln 2 = 0.693; R = 8.314 J mol⁻¹ K⁻¹)