The incorrect statement from the following with respect to carbohydrates is :

Which of the following amino acid will give violet coloured complex with neutral ferric chloride solution?

Number of paramagnetic complexes among the following is $\_\_\_\_$ .

$$ \begin{aligned} & {\left[\mathrm{MnBr}_4\right]^{2-},\left[\mathrm{NiCl}_4\right]^{2-},\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-},\left[\mathrm{Ni}(\mathrm{CO})_4\right],\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-},\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-},\left[\mathrm{Ti}(\mathrm{CN})_6\right]^{3-},} \\ & {\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}} \end{aligned} $$

' $x$ ' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. ' $y$ ' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous $\mathrm{AlCl}_3$. Product (major) obtained by heating $x$ and $y$ in the presence of alkali is $z$. Total number of $\pi$ (pi) electrons in $z$ is $\_\_\_\_$ .