Given below are two statements :

Statement I : The number of pairs among $\left[\mathrm{Ti}^{4+}, \mathrm{V}^{2+}\right],\left[\mathrm{V}^{2+}, \mathrm{Mn}^{2+}\right],\left[\mathrm{Mn}^{2+}, \mathrm{Fe}^{3+}\right]$ and $\left[\mathrm{V}^{2+}, \mathrm{Cr}^{2+}\right]$ in which both ions are coloured is 3 .

Statement II : The number of pairs among $\left[\mathrm{La}^{3+}, \mathrm{Yb}^{2+}\right],\left[\mathrm{Lu}^{3+}, \mathrm{Ce}^{4+}\right]$ and $\left[\mathrm{Ac}^{3+}, \mathrm{Lr}^{3+}\right]$ ions in which both are diamagnetic is 3 .

In the light of the above statements, choose the correct from the options given below :

Given below are two statements for catalytic properties of transition metals.

Statement I : First row transition metals which act as catalyst utilise their 3d electrons only for formation of bonds between reactant molecules and atoms on the surface of catalyst.

Statement II : There is increase in the concentration of reactants on the surface of catalyst which strengthens the bonds in reacting molecules.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements :

Statement I : Vapours of the liquid with higher boiling point condense before vapours of the liquid with lower boiling points in fractional distillation.

Statement II : The vapours rising up in the fractionating column become richer in high boiling component of the mixture.

In the light of the above statements, choose the correct answer from the options given below :

$$ \text { The major product of which of the following reaction is not obtained by rearrangement reaction? } $$