JEE Main Ultimate Online Test Series - 2027
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$$ \text { Consider the following data. } $$
$$ \begin{array}{|c|c|} \hline \text { Electrolyte } & \wedge^{\circ}_\mathbf{m}{\mathbf{(}} \mathbf{S ~ c m}^{\mathbf{2}} \mathbf{~ m o l}^{\mathbf{1}} \mathbf{)} \\ \hline \mathrm{BaCl}_2 & x_1 \\ \hline \mathrm{H}_2 \mathrm{SO}_4 & x_2 \\ \hline \mathrm{HCl} & x_3 \\ \hline \end{array} $$
$\mathrm{BaSO}_4$ is sparingly soluble in water. If the conductivity of the saturated $\mathrm{BaSO}_4$ solution is $x \mathrm{~S} \mathrm{~cm}^{-1}$ then the solubility product of $\mathrm{BaSO}_4$ can be given as (Here $\wedge_{\mathrm{m}}=\wedge^{\circ}_{\mathrm{m}}$ )
Given below are two statements :
Statement I : Aluminium is more electropositive than thallium as the standard electrode potential value of $\mathrm{E}^{\circ} \mathrm{Al}^{3+} / \mathrm{Al}$ is negative and $\mathrm{E}^{\circ} \mathrm{Tl}^{3+} / \mathrm{Tl}$ is positive.
Statement II : The sum of first three ionization enthalpies of boron is very high when compared to that of aluminium. Due to this reason boron forms covalent compounds only and aluminium forms $\mathrm{Al}^{3+}$ ion.
In the light of the above statements, choose the correct answer from the options given below
The correct statements among the following are :
A. Basic vanadium oxide is used in the manufacture of $\mathrm{H}_2 \mathrm{SO}_4$.
B. The spin-only magnetic moment value of the transition metal halide employed in Ziegler-Natta polymerization is 2.84 BM .
C. The p-block metal compound employed in Ziegler-Natta polymerization has the metal in +3 oxidation state.
D. The number of electrons present in the outer most ' d ' orbital of metal halide employed in Wacker process is 8.
Choose the correct answer from the options given below :
$$ \text { Match the LIST-I with LIST-II } $$
| List-I Electronic configuration of tetrahedral metal ion |
$$ \begin{gathered} \text { List-II } \\ \text { Crystal Field Stabilization } \\ \text { Energy }\left(\Delta_t\right) \end{gathered} $$ |
||
|---|---|---|---|
| A. | $$ \mathrm{d}^2 $$ |
I. | -0.6 |
| B. | $$ \mathrm{d}^4 $$ |
II. | -0.8 |
| C. | $$ \mathrm{d}^6 $$ |
III. | -1.2 |
| D. | $$ \mathrm{d}^8 $$ |
IV. | -0.4 |
Choose the correct answer from the options given below:
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