One mole each of He and $\mathrm{A}(\mathrm{g})$ are taken in a 10 L closed flask and heated to 400 K to establish the following equilibrium.

$$ \mathrm{A}(\mathrm{~g}) \rightleftharpoons \mathrm{B}(\mathrm{~g}) $$

$\mathrm{K}_{\mathrm{c}}$ for this reaction at 400 K is 4.0 . The partial pressures (in atm) of He and B(g) are respectively (at equilibrium)

(Assume $\mathrm{He}, \mathrm{A}(\mathrm{g})$ and $\mathrm{B}(\mathrm{g})$ behave as ideal gases)

(Given : $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ )

$$ \text { Consider the following data. } $$

$$ \begin{array}{|c|c|} \hline \text { Electrolyte } & \wedge^{\circ}_\mathbf{m}{\mathbf{(}} \mathbf{S ~ c m}^{\mathbf{2}} \mathbf{~ m o l}^{\mathbf{1}} \mathbf{)} \\ \hline \mathrm{BaCl}_2 & x_1 \\ \hline \mathrm{H}_2 \mathrm{SO}_4 & x_2 \\ \hline \mathrm{HCl} & x_3 \\ \hline \end{array} $$

$\mathrm{BaSO}_4$ is sparingly soluble in water. If the conductivity of the saturated $\mathrm{BaSO}_4$ solution is $x \mathrm{~S} \mathrm{~cm}^{-1}$ then the solubility product of $\mathrm{BaSO}_4$ can be given as (Here $\wedge_{\mathrm{m}}=\wedge^{\circ}_{\mathrm{m}}$ )

Given below are two statements :

Statement I : Aluminium is more electropositive than thallium as the standard electrode potential value of $\mathrm{E}^{\circ} \mathrm{Al}^{3+} / \mathrm{Al}$ is negative and $\mathrm{E}^{\circ} \mathrm{Tl}^{3+} / \mathrm{Tl}$ is positive.

Statement II : The sum of first three ionization enthalpies of boron is very high when compared to that of aluminium. Due to this reason boron forms covalent compounds only and aluminium forms $\mathrm{Al}^{3+}$ ion.

In the light of the above statements, choose the correct answer from the options given below

The correct statements among the following are :

A. Basic vanadium oxide is used in the manufacture of $\mathrm{H}_2 \mathrm{SO}_4$.

B. The spin-only magnetic moment value of the transition metal halide employed in Ziegler-Natta polymerization is 2.84 BM .

C. The p-block metal compound employed in Ziegler-Natta polymerization has the metal in +3 oxidation state.

D. The number of electrons present in the outer most ' d ' orbital of metal halide employed in Wacker process is 8.

Choose the correct answer from the options given below :