20 mL of a solution of acetic acid required 28.4 mL of 0.1 M NaOH for its neutralization. A solution (X) was prepared by mixing 20 mL of the above acetic acid and 14.2 mL of 0.1 M NaOH solution. What is the pH of the solution $(\mathrm{X})$ ? $\left(\mathrm{pK}_{\mathrm{a}}\right.$ value of acetic acid is 4.75).
$$ \text { Match the LIST-I with LIST-II } $$
| List-I Reaction |
List-I Mechanism |
||
|---|---|---|---|
| A. | Williamson Synthesis | I. | Electrophilic addition |
| B. | Friedel Craft Reaction | II. | Free radical substitution |
| C. | Bromination of vinyl benzene | III. | Nucleophilic substitution |
| D. | Chlorination of toluene in light | IV. | Electrophilic substitution |
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The $1^{\text {st }}$ ionization enthalpy for Mg is $+737 \mathrm{~kJ} / \mathrm{mol}$. The most probable estimated value of the $2^{\text {nd }}$ ionization enthalpy of Mg is $\_\_\_\_$ .
The electronegativity of a group 13 element ' E ' is same as that of Ge (on Pauling scale and upto one decimal point). The CORRECT statements about $\mathrm{E}^{3+}$ are
A. It can act as a reducing agent.
B. It can act as an oxidizing agent.
C. $\mathrm{E}^{3+}$ is more stable than $\mathrm{E}^{+}$.
D. The standard electrode potential value for $\mathrm{E}^{3+} / \mathrm{E}$ is positive.
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