$$ \text { Given below are the four isomeric compounds }(\mathrm{P}, \mathrm{Q}, \mathrm{R}, \mathrm{~S}) $$

Identify correct statements from below.

A. $\mathrm{Q}, \mathrm{R}$ and S will give precipitate with 2, 4-DNP.

B. $P$ and $Q$ will give positive Bayer's test.

C. Q and R will give sooty flame.

D. R and S will give yellow precipitate with $\mathrm{I}_2 / \mathrm{NaOH}$.

E. Q alone will deposit silver with Tollen's reagent

Choose the correct option.

Consider a weak base ' B ' of $\mathrm{pK}_{\mathrm{b}}=5.699$. ' $x$ ' mL of 0.02 M HCl and ' y ' mL of 0.02 M weak base ' B ' are mixed to make 100 mL of a buffer of pH 9 at $25^{\circ} \mathrm{C}$. The values of ' $x$ ' and ' $y$ ' respectively are :

[Given : $\log 2=0.3010, \log 3=0.4771, \log 5=0.699$ ]

Given below are two statements:

Statement I : Griss-Ilosvay test is used for the detection of nitrite ion, which involves the use of sulphanilic acid and $\alpha$-naphthylamine reagent.

Statement II : In the above test, sulphanilic acid is diazotized by the acidified nitrite ion, which on further coupling with $\alpha$-naphthylamine forms an azo-dye.

In the light of the above statements, choose the correct answer from the options given below

Consider the following reactions giving major product. Identify the correct reaction.