Among the following, the CORRECT combinations are

A. $\mathrm{IF}_3 \rightarrow \mathrm{~T}$-shaped ( $\mathrm{sp}^3 \mathrm{~d}$ )

B. $\mathrm{IF}_5 \rightarrow$ Square pyramidal $\left(\mathrm{sp}^3 \mathrm{~d}^2\right)$

C. $\mathrm{IF}_7 \rightarrow$ Pentagonal bipyramidal $\left(\mathrm{sp}^3 \mathrm{~d}^3\right)$

D. $\mathrm{ClO}_4{ }^{-} \rightarrow$ Square planar ( $\mathrm{sp}^2 \mathrm{~d}$ )

Choose the correct answer from the options given below:

$\mathrm{A} \rightarrow \mathrm{D}$ is an endothermic reaction occurring in three steps (elementary).

(i) $\mathrm{A} \rightarrow \mathrm{B} \Delta \mathrm{H}_i=+\mathrm{ve}$

(ii) $\mathrm{B} \rightarrow \mathrm{C} \Delta \mathrm{H}_{i i}=-\mathrm{ve}$

(iii) $\mathrm{C} \rightarrow \mathrm{D} \Delta \mathrm{H}_{i i i}=-\mathrm{ve}$

Which of the following graphs between potential energy ( $y$-axis) vs reaction coordinate ( $x$-axis) correctly represents the reaction profile of $A \rightarrow D$ ?

Consider a mixture ' X ' which is made by dissolving 0.4 mol of $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{SO}_4\right] \mathrm{Br}$ and 0.4 mol of $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Br}\right] \mathrm{SO}_4$ in water to make 4 L of solution. When 2 L of mixture ' X ' is allowed to react with excess of $\mathrm{AgNO}_3$, it forms precipitate ' Y '. The rest 2 L of mixture ' X ' reacts with excess $\mathrm{BaCl}_2$ to form precipitate ' Z '. Which of the following statements is CORRECT?

$$ \text { Consider the following two reactions } \mathrm{A} \text { and } \mathrm{B} \text {. } $$

Numerical value of [molar mass of $x+$ molar mass of $y$ ] is $\_\_\_\_$