In Dumas method for estimation of nitrogen, 0.50 g of an organic compound gave 70 mL of nitrogen collected at 300 K and 715 mm pressure. The percentage of nitrogen in the organic compound is $\_\_\_\_$ $\%$.

(Aqueous tension at 300 K is 15 mm ).

X and Y are the number of electrons involved, respectively during the oxidation of $\mathrm{I}^{-}$to $\mathrm{I}_2$ and $\mathrm{S}^{2-}$ to S by acidified $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$. The value of $\mathrm{X}+\mathrm{Y}$ is $\_\_\_\_$ .

Let $\vec{a}=2 \hat{\mathrm{i}}+\hat{\mathrm{j}}-2 \hat{\mathrm{k}}, \vec{b}=\hat{\mathrm{i}}+\hat{\mathrm{j}}$ and $\vec{c}=\vec{a} \times \vec{b}$. Let $\vec{d}$ be a vector such that $|\vec{d}-\vec{a}|=\sqrt{11},|\vec{c} \times \vec{d}|=3$ and the angle between $\vec{c}$ and $\vec{d}$ is $\frac{\pi}{4}$. Then $\vec{a} \cdot \vec{d}$ is equal to

Let $A(1,0), B(2,-1)$ and $C\left(\frac{7}{3}, \frac{4}{3}\right)$ be three points. If the equation of the bisector of the angle ABC is $\alpha x+\beta y=5$, then the value of $\alpha^2+\beta^2$ is