The energy of first (lowest) Balmer line of H atom is $x \mathrm{~J}$. The energy (in J) of second Balmer line of H atom is :

Given below are two statements :

Statement I : The first ionization enthalpy of Cr is lower than that of Mn .

Statement II : The second and third ionization enthalpies of Cr are higher than those of Mn .

In the light of the above statements, choose the correct answer from the options given below :

At $\mathrm{T}(\mathrm{K}), 100 \mathrm{~g}$ of $98 \% \mathrm{H}_2 \mathrm{SO}_4(\mathrm{w} / \mathrm{w})$ aqueous solution is mixed with 100 g of $49 \% \mathrm{H}_2 \mathrm{SO}_4(\mathrm{w} / \mathrm{w})$ aqueous solution. What is the mole fraction of $\mathrm{H}_2 \mathrm{SO}_4$ in the resultant solution?

(Given : Atomic mass $\mathrm{H}=1 \mathrm{u} ; \mathrm{S}=32 \mathrm{u} ; \mathrm{O}=16 \mathrm{u}$ ).

(Assume that temperature after mixing remains constant)

$$ \text { 3, 3-Dimethyl-2-butanol cannot be prepared by : } $$

$$ \text { Choose the correct answer from the options given below : } $$