Consider the following reduction processes :
$$ \begin{aligned} & \mathrm{Al}^{3+}+3 \mathrm{e}^{-} \longrightarrow \mathrm{Al}(\mathrm{~s}), \mathrm{E}^0=-1.66 \mathrm{~V} \\ & \mathrm{Fe}^{3+}+\mathrm{e}^{-} \longrightarrow \mathrm{Fe}^{2+}, \mathrm{E}^0=+0.77 \mathrm{~V} \\ & \mathrm{Co}^{3+}+\mathrm{e}^{-} \longrightarrow \mathrm{Co}^{2+}, \mathrm{E}^0=+1.81 \mathrm{~V} \\ & \mathrm{Cr}^{3+}+3 \mathrm{e}^{-} \longrightarrow \mathrm{Cr}(\mathrm{~s}), \mathrm{E}^0=-0.74 \mathrm{~V} \end{aligned} $$
The tendency to act as reducing agent decreases in the order :
The compound $\mathrm{A}, \mathrm{C}_8 \mathrm{H}_8 \mathrm{O}_2$ reacts with acetophenone to form a single product via cross-Aldol condensation. The compound A on reaction with conc. NaOH forms a substituted benzyl alcohol as one of the two products. The compound A is :
$$ \text { Match List - I with List - II. } $$
| List - I Reaction of Glucose with |
List - II Product formed |
||
|---|---|---|---|
| A. | Hydroxylamine | I. | Gluconic acid |
| B. | $\mathrm{Br}_2$ water | II. | Glucose pentacetate |
| C. | Excess acetic anhydride | III. | Saccharic acid |
| D. | Concentrated $\mathrm{HNO}_3$ | IV. | Glucoxime |
Choose the correct answer from the options given below :
Identify the correct statements :
A. Hydrated salts can be used as primary standard.
B. Primary standard should not undergo any reaction with air.
C. Reactions of primary standard with another substance should be instantaneous and stoichiometric.
D. Primary standard should not be soluble in water.
E. Primary standard should have low relative molar mass.
Choose the correct answer from the options given below :
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