The octahedral diamagnetic low spin complex among the following is :
Using column chromatography, mixture of two compounds 'A' and 'B' was separated. 'A' eluted first, this indicates 'B' has
Given
| (A) | $$\mathrm{2CO(g)+O_2(g)\to 2CO_2(g)}$$ | $$\mathrm{\Delta H_1^0=-x~kJ~mol^{-1}}$$ | |
|---|---|---|---|
| (B) | $$\mathrm{C(graphite)+O_2(g)\to CO_2(g)}$$ | $$\mathrm{\Delta H_2^0=-y~kJ~mol^{-1}}$$ |
$$\mathrm{\Delta H^0}$$ for the reaction
$$\mathrm{C(graphite)+\frac{1}{2}O_2(g)\to CO(g)}$$ is :
Isomeric amines with molecular formula C$$_8$$H$$_{11}$$N give the following tests
Isomer (P) $$\Rightarrow$$ Can be prepared by Gabriel phthalimide synthesis
Isomer (Q) $$\Rightarrow$$ Reacts with Hinsberg's reagent to give solid insoluble in NaOH
Isomer (R) $$\Rightarrow$$ Reacts with HONO followed by $$\beta$$-naphthol in NaOH to give red dye.
Isomers (P), (Q) and (R) respectively are
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