Using the provided information in the following paper chromatogram :


Fig : Paper chromatography for compounds A and B.

the calculated R_f value of A ________$$\times$$ 10^-1.

The reaction of cyanamide, NH₂CN_(s) with oxygen was run in a bomb calorimeter and $$\Delta$$U was found to be $$-$$742.24 kJ mol^$$-$$1. The magnitude of $$\Delta$$H₂₉₈ for the reaction

$$N{H_2}C{H_{(S)}} + {3 \over 2}{O_{2(g)}} \to {N_{2(g)}} + {O_{2(g)}} + {H_2}{O_{(I)}}$$

is _________ kJ. (Rounded off to the nearest integer) [Assume ideal gases and R = 8.314 J mol^$$-$$1 K^$$-$$1]

The ionization enthalpy of Na⁺ formation from Na_(g) is 495.8 kJ mol^$$-$$1, while the electron gain enthalpy of Br is $$-$$325.0 kJ mol^$$-$$1. Given the lattice enthalpy of NaBr is $$-$$728.4 kJ mol^$$-$$1. The energy for the formation of NaBr ionic solid is ($$-$$) ____________ $$\times$$ 10^$$-$$1 kJ mol^$$-$$1.

0.4 g mixture of NaOH, Na₂CO₃ and some inert impurities was first titrated with $${N \over {10}}$$ HCl using phenolphthalein as an indicator, 17.5 mL of HCl was required at the end point. After this methyl orange was added and titrated. 1.5 mL of same HCl was required for the next end point. The weight percentage of Na₂CO₃ in the mixture is ________. (Rounded off to the nearest integer)