A 6.50 molal solution of KOH (aq.) has a density of 1.89 g cm^$$-$$3. The molarity of the solution is ____________ mol dm^$$-$$3. (Round off to the Nearest Integer).

[Atomic masses : K : 39.0 u; O : 16.0 u; H : 1.0 u]

AB₂ is 10% dissociated in water to A²⁺ and B^$$-$$. The boiling point of a 10.0 molal aqueous solution of AB₂ is __________$$^\circ$$C. (Round off to the Nearest Integer).

[Given : Molal elevation constant of water K_b = 0.5 K kg mol^$$-$$1 boiling point of pure water = 100$$^\circ$$C]

When light of wavelength 248 nm falls on a metal of threshold energy 3.0 eV, the de-Broglie wavelength of emitted electrons is _______$$\mathop A\limits^o $$. (Round off to the Nearest Integer).

[ Use : $$\sqrt 3 $$ = 1.73, h = 6.63 $$\times$$ 10^$$-$$34 Js

m_e = 9.1 $$\times$$ 10^$$-$$31 kg; c = 3.0 $$\times$$ 10⁸ ms^$$-$$1; 1eV = 1.6 $$\times$$ 10^$$-$$19 J]

The decomposition of formic acid on gold surface follows first order kinetics. If the rate constant at 300 K is 1.0 $$\times$$ 10^$$-$$3 s^$$-$$1 and the activation energy E_a = 11.488 kJ mol^$$-$$1, the rate constant at 200 K is ____________ $$\times$$ 10^$$-$$5 s^$$-$$1. (Round off to the Nearest Integer). (Given : R = 8.314 J mol^$$-$$1 K^$$-$$1)