The increasing order of basicity of the following compounds is :

In the sixth period, the orbitals that are filled are :

If the function
$$f\left( x \right) = \left\{ {\matrix{ {{k_1}{{\left( {x - \pi } \right)}^2} - 1,} & {x \le \pi } \cr {{k_2}\cos x,} & {x > \pi } \cr } } \right.$$ is
twice differentiable, then the ordered pair (k₁, k₂) is equal to :

If the minimum and the maximum values of the function $$f:\left[ {{\pi \over 4},{\pi \over 2}} \right] \to R$$, defined by
$$f\left( \theta \right) = \left| {\matrix{ { - {{\sin }^2}\theta } & { - 1 - {{\sin }^2}\theta } & 1 \cr { - {{\cos }^2}\theta } & { - 1 - {{\cos }^2}\theta } & 1 \cr {12} & {10} & { - 2} \cr } } \right|$$ are m and M respectively, then the ordered pair (m,M) is equal to :