Simplified absorption spectra of three complexes ((i), (ii) and (iii)) of Mn⁺ ion are provided below; their $$\lambda $$_max values are marked as A, B and C respectively. The correct match between the complexes and their $$\lambda $$_max values is
(i) [M(NCS)₆]^{(–6 + n)}
(ii) [MF₆]^{(–6 + n)}
(iii) [M(NH₃)₆]ⁿ⁺

The heat of combustion of ethanol into carbon dioxide and water is – 327 kcal at constant pressure. The heat evolved (in cal) at constant volume and 27^oC (if all gases behave ideally) is (R = 2 cal mol^–1 K^–1) ________.

The shape / structure of [XeF₅]^– and XeO₃F₂, respectively, are

The correct observation in the following reactions is :