At $$310 \mathrm{~K}$$, the solubility of $$\mathrm{CaF}_{2}$$ in water is $$2.34 \times 10^{-3} \mathrm{~g} / 100 \mathrm{~mL}$$. The solubility product of $$\mathrm{CaF}_{2}$$ is ____________ $$\times 10^{-8}(\mathrm{~mol} / \mathrm{L})^{3}$$. (Give molar mass : $$\mathrm{CaF}_{2}=78 \mathrm{~g} \mathrm{~mol}^{-1}$$)
In the titration of $$\mathrm{KMnO}_{4}$$ and oxalic acid in acidic medium, the change in oxidation number of carbon at the end point is ___________.
At $$298 \mathrm{~K}$$, the equilibrium constant is $$2 \times 10^{15}$$ for the reaction :
$$\mathrm{Cu}(\mathrm{s})+2 \mathrm{Ag}^{+}(\mathrm{aq}) \rightleftharpoons \mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{Ag}(\mathrm{s})$$
The equilibrium constant for the reaction
$$ \frac{1}{2} \mathrm{Cu}^{2+}(\mathrm{aq})+\mathrm{Ag}(\mathrm{s}) \rightleftharpoons \frac{1}{2} \mathrm{Cu}(\mathrm{s})+\mathrm{Ag}^{+}(\mathrm{aq}) $$
is $$x \times 10^{-8}$$. The value of $$x$$ is _____________. (Nearest Integer)
2NOCl(g) $$\rightleftharpoons$$ 2NO(g) + Cl2(g)
In an experiment, 2.0 moles of NOCl was placed in a one-litre flask and the concentration of NO after equilibrium established, was found to be 0.4 mol/L. The equilibrium constant at 30$$^\circ$$C is ______________ $$\times$$ 10$$-$$4.