In order to prepare a buffer solution of pH 5.74, sodium acetate is added to acetic acid. If the concentration of acetic acid in the buffer is 1.0 M, the concentration of sodium acetate in the buffer is ___________ M. (Round off to the Nearest Integer). [Given : pKa (acetic acid) = 4.74]

Sulphurous acid (H₂SO₃) has Ka₁ = 1.7 $$\times$$ 10^$$-$$2 and Ka₂ = 6.4 $$\times$$ 10^$$-$$8. The pH of 0.588 M H₂SO₃ is __________. (Round off to the Nearest Integer).

Two salts A₂X and MX have the same value of solubility product of 4.0 $$\times$$ 10^$$-$$12. The ratio of their molar solubilities i.e. $${{S({A_2}X)} \over {S(MX)}}$$ = __________. (Round off to the Nearest Integer)

The pH of ammonium phosphate solution, if pk_a of phosphoric acid and pk_b of ammonium hydroxide are 5.23 and 4.75 respectively, is ___________.