A sample of $$0.125 \mathrm{~g}$$ of an organic compound when analyzed by Duma's method yields $$22.78 \mathrm{~mL}$$ of nitrogen gas collected over $$\mathrm{KOH}$$ solution at $$280 \mathrm{~K}$$ and $$759 \mathrm{~mm}\, \mathrm{Hg}$$. The percentage of nitrogen in the given organic compound is __________. (Nearest integer)

Given :

(a) The vapour pressure of water of $$280 \mathrm{~K}$$ is $$14.2 \mathrm{~mm} \,\mathrm{Hg}$$.

(b) $$\mathrm{R}=0.082 \mathrm{~L}$$ atm $$\mathrm{K}^{-1} \mathrm{~mol}^{-1}$$

In the above reaction, $$5 \mathrm{~g}$$ of toluene is converted into benzaldehyde with $$92 \%$$ yield. The amount of benzaldehyde produced is ______________ $$\times 10^{-2} \mathrm{~g}$$. (Nearest integer)

The separation of two coloured substances was done by paper chromatography. The distances travelled by solvent front, substance A and substance B from the base line are 3.25 cm, 2.08 cm and 1.05 cm, respectively. The ratio of R_{f} values of A to B is _____________.

While estimating the nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from $$0.25 \mathrm{~g}$$ of the compound neutralized $$2.5 \mathrm{~mL}$$ of $$2 \,\mathrm{M} \,\mathrm{H}_{2} \mathrm{SO}_{4}$$. The percentage of nitrogen present in organic compound is ______________.