A 2.0 g sample containing MnO2 is treated with HCl liberating Cl2. The Cl2 gas is passed into a solution of KI and 60.0 mL of 0.1 M Na2S2O3 is required to titrate the liberated iodine. The percentage of MnO2 in the sample is _____________. (Nearest integer)
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]
In the estimation of bromine, 0.5 g of an organic compound gave 0.40 g of silver bromide. The percentage of bromine in the given compound is _________ % (nearest integer)
(Relative atomic masses of Ag and Br are 108u and 80u, respectively).
0.25 g of an organic compound containing chlorine gave 0.40 g of silver chloride in Carius estimation. The percentage of chlorine present in the compound is ___________. [in nearest integer]
(Given : Molar mass of Ag is 108 g mol$$-$$1 and that of Cl is 35.5 g mol$$-$$1)
0.2 g of an organic compound was subjected to estimation of nitrogen by Dumas method in which volume of N2 evolved (at STP) was found to be 22.400 mL. The percentage of nitrogen in the compound is _________. [nearest integer]
(Given : Molar mass of N2 is 28 g mol$$-$$1. Molar volume of N2 at STP : 22.4 L)