On a thin layer chromatographic plate, an organic compound moved by $$3.5 \mathrm{~cm}$$, while the solvent moved by $$5 \mathrm{~cm}$$. The retardation factor of the organic compound is ________ $$\times 10^{-1}$$.

$$0.400 \mathrm{~g}$$ of an organic compound $$(\mathrm{X})$$ gave $$0.376 \mathrm{~g}$$ of $$\mathrm{AgBr}$$ in Carius method for estimation of bromine. $$\%$$ of bromine in the compound $$(\mathrm{X})$$ is ___________.

(Given: Molar mass $$\mathrm{AgBr=188~g~mol^{-1}}$$

$$\mathrm{Br}=80 \mathrm{~g} \mathrm{~mol}^{-1}$$)

$$\mathrm{KMnO}_{4}$$ is titrated with ferrous ammonium sulphate hexahydrate in presence of dilute $$\mathrm{H}_{2} \mathrm{SO}_{4}$$. Number of water molecules produced for 2 molecules of $$\mathrm{KMnO}_{4}$$ is ___________.