$$250 \mathrm{~g}$$ solution of $$\mathrm{D}$$-glucose in water contains $$10.8 \%$$ of carbon by weight. The molality of the solution is nearest to

(Given: Atomic Weights are, $$\mathrm{H}, 1 \,\mathrm{u} ; \mathrm{C}, 12 \,\mathrm{u} ; \mathrm{O}, 16 \,\mathrm{u}$$)

In Carius method of estimation of halogen, $$0.45 \mathrm{~g}$$ of an organic compound gave $$0.36 \mathrm{~g}$$ of $$\mathrm{AgBr}$$. Find out the percentage of bromine in the compound.

(Molar masses : $$\mathrm{AgBr}=188 \mathrm{~g} \mathrm{~mol}^{-1} ; \mathrm{Br}=80 \mathrm{~g} \mathrm{~mol}^{-1}$$)

Hemoglobin contains $$0.34 \%$$ of iron by mass. The number of Fe atoms in $$3.3 \mathrm{~g}$$ of hemoglobin is

(Given: Atomic mass of Fe is $$56 \,\mathrm{u}, \mathrm{N}_{\mathrm{A}}=6.022 \times 10^{23} \mathrm{~mol}^{-1}$$.)

$$\mathrm{SO}_{2} \mathrm{Cl}_{2}$$ on reaction with excess of water results into acidic mixture

$$\mathrm{SO}_{2} \mathrm{Cl}_{2}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{H}_{2} \mathrm{SO}_{4}+2 \mathrm{HCl}$$

16 moles of $$\mathrm{NaOH}$$ is required for the complete neutralisation of the resultant acidic mixture. The number of moles of $$\mathrm{SO}_{2} \mathrm{Cl}_{2}$$ used is :