$$ \text { In the following reactions, which one is NOT correct? } $$

When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid $(273 \mathrm{~K})$ and acidified with acetic acid, the mass $(\mathrm{g})$ of 0.1 mole of product formed is :

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, \mathrm{O}: 16, \mathrm{~S}: 32$ )

The correct order of basic nature in aqueous solution for the bases $\mathrm{NH}_3, \mathrm{H}_2 \mathrm{~N}-\mathrm{NH}_2, \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2,\left(\mathrm{CH}_3 \mathrm{CH}_2\right)_2 \mathrm{NH}$ and $\left(\mathrm{CH}_3 \mathrm{CH}_2\right)_3 \mathrm{~N}$ is :

Which one of the following reaction sequences will give an azo dye?