5 L of an alkane requires 25 L of oxygen for its complete combustion. If all volumes are measured at constant temperature and pressure, the alkane is :

At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O₂ by volume for complete combustion. After combustion the gases occupy 345 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:

The reaction of propene with HOCl (Cl₂ + H₂O) proceeds through the intermediate:

Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one isomer of mono substituted alkyl halide ?