Given below are two statements :
Statement I : In
, the carbocation is stabilised by +R effect of –OCH3 group.
Statement II : In
, the carbanion is stabilised by –R effect of –NO2 group.
In the light of the above statements, choose the correct answer from the options given below :
The compound (X) on
(i) on heating in the presence of anhydrous AlCl3 and HCl gas gives 2,4-dimethyl pentane
(ii) aromatization gives toluene and
(iii) cyclisation gives methyl cyclohexane
The correct name of compound (X) is:
Correct statements regarding alkyl halides (R–X) among the following are :
A. Alcohol being less polar solvent as compared to water, alcoholic KOH favours elimination reaction with R–X.
B. Order of reactivity towards SN1 mechanism is C6H5–CH2–Cl > C6H5–CHCl–C6H5.
C. Non substituted aryl halides exhibit properties similar to alkyl halides.
D. Vinyl chloride is an example of haloalkene and allyl chloride is an example of haloalkyne.
E. R–Cl can be prepared by reacting R–OH with SOCl2 but Ar–Cl cannot be prepared by reacting Ar–OH with SOCl2.
Choose the correct answer from the options given below :
An organic compound “x” where molar ratio of C, O and H are equal, on treatment with 50% KOH under reflux followed by acidification produced “y”. The most likely structure of “y” is:
[Molar mass of ‘x’ is 58 g mol−1]
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