Grignard reagent $\mathrm{RMgBr}(\mathrm{P})$ reacts with water and forms a gas $(\mathrm{Q})$. One gram of Q occupies $1.4 \mathrm{dm}^3$ at STP. (P) on reaction with dry ice in dry ether followed by $\mathrm{H}_3 \mathrm{O}^{+}$forms a compound (Z). 0.1 mole of (Z) will weigh $\_\_\_\_$ g. (Nearest integer)

Molar conductivity of a weak acid HQ of concentration 0.18 M was found to be $1 / 30$ of the molar conductivity of another weak acid HZ with concentration of 0.02 M . If $\lambda^{\circ} \mathrm{Q}^{-}$happened to be equal with $\lambda^{\circ} \mathrm{Z}^{-}$, then the difference of the $\mathrm{pK}_{\mathrm{a}}$ values of the two weak acids $\left(\mathrm{pK}_{\mathrm{a}}(\mathrm{HQ})-\mathrm{pK}_{\mathrm{a}}(\mathrm{HZ})\right)$ is $\_\_\_\_$ (Nearest integer).

[Given: degree of dissociation $(\alpha) \ll 1$ for both weak acids, $\lambda^{\circ}$ : limiting molar conductivity of ions]

A chromium complex with a formula $\mathrm{CrCl}_3 \cdot 6 \mathrm{H}_2 \mathrm{O}$ has a spin only magnetic moment value of 3.87 BM and its solution conductivity corresponds to $1: 2$ electrolyte. 2.75 g of the complex solution was initially passed through a cation exchanger. The solution obtained after the process was reacted with excess of $\mathrm{AgNO}_3$. The amount of AgCl formed in the above process is $\_\_\_\_$ g. (Nearest integer)

[Given: Molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{Cr}: 52 ; \mathrm{Cl}: 35.5, \mathrm{Ag}: 108, \mathrm{O}: 16, \mathrm{H}: 1$ ]

The half-life of ${ }^{65} \mathrm{Zn}$ is 245 days. After $x$ days, $75 \%$ of original activity remained. The value of $x$ in days is $\_\_\_\_$ . (Nearest integer)

(Given: $\log 3=0.4771$ and $\log 2=0.3010$ )