Given below are two statements :
Statement I : $\left[\mathrm{CoBr}_4\right]^{2-}$ ion will absorb light of lower energy than $\left[\mathrm{CoCl}_4\right]^{2-}$ ion.
Statement II : In $\left[\mathrm{CoI}_4\right]^{2-}$ ion, the energy separation between the two set of d-orbitals is more than $\left[\mathrm{CoCl}_4\right]^{2-}$ ion.
In the light of the above statements, choose the correct answer from the options given below :
Which of the following statements regarding the energy of the stationary state is true in the following one - electron systems ?
The crystal field splitting energy of $\left[\mathrm{Co}(\text { oxalate })_3\right]^{3-}$ complex is ' $n^{\prime}$ times that of the $\left[\mathrm{Cr}(\text { oxalate })_3\right]^{3-}$ complex. Here ' $n$ ' is $\_\_\_\_$ . (Assume $\Delta_0 \gg P$ )
For the following gas phase equilibrium reaction at constant temperature,
$$ \mathrm{NH}_3(\mathrm{~g}) \rightleftharpoons 1 / 2 \mathrm{~N}_2(\mathrm{~g})+3 / 2 \mathrm{H}_2(\mathrm{~g}) $$
if the total pressure is $\sqrt{3} \mathrm{~atm}$ and the pressure equilibrium constant $\left(K_p\right)$ is 9 atm , then the degree of dissociation is given as $\left(x \times 10^{-2}\right)^{-1 / 2}$. The value of $x$ is $\_\_\_\_$ . (nearest integer)
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