Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : At 10$$^\circ$$C, the density of a 5 M solution of KCl [atomic masses of K & Cl are 39 & 35.5 g mol$$-$$1 respectively], is 'x' g ml$$-$$1. The solution is cooled to $$-$$21$$^\circ$$C. The molality of the solution will remain unchanged.
Reason (R) : The molality of a solution does not change with temperature as mass remains unaffected with temperature.
In the light of the above statements, choose the correct answer from the options given below :
Based upon VSEPR theory, match the shape (geometry) of the molecules in List-I with the molecules in List-II and select the most appropriate option.
List - I (Shape) |
List - II (Molecules) |
||
---|---|---|---|
(A) | T-shaped | (I) | XeF$$_4$$ |
(B) | Trigonal planar | (II) | SF$$_4$$ |
(C) | Square planar | (III) | ClF$$_3$$ |
(D) | See-saw | (IV) | BF$$_3$$ |
Match List-I with List-II.
List - I | List - II | ||
---|---|---|---|
(A) | Spontaneous process | (I) | $$\Delta H < 0$$ |
(B) | Process with $$\Delta P = 0$$, $$\Delta T = 0$$ | (II) | $$\Delta {G_{T,P}} < 0$$ |
(C) | $$\Delta {H_{reaction}}$$ | (III) | Isothermal and isobaric process |
(D) | Exothermic Process | (IV) | [Bond energies of molecules in reactants] $$ - $$ [Bond energies of product molecules |
Choose the correct answer from the options given below :
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : The ionic radii of O2$$-$$ and Mg2+ are same.
Reason (R) : Both O2$$-$$ and Mg2+ are isoelectronic species.
In the light of the above statements, choose the correct answer from the options given below.