For the galvanic cell,

Zn(s) + Cu²⁺ (0.02 M) $$\to$$ Zn²⁺ (0.04 M) + Cu(s),

E_cell = ______________ $$\times$$ 10^$$-$$2 V. (Nearest integer)

[Use : $$E_{Cu/C{u^{2 + }}}^0$$ = $$-$$ 0.34 V, $$E_{Zn/Z{n^{2 + }}}^0$$ = + 0.76 V, $${{2.303RT} \over F} = 0.059\,V$$]

100 mL of Na₃PO₄ solution contains 3.45 g of sodium. The molarity of the solution is _____________ $$\times$$ 10^$$-$$2 mol L^$$-$$1. (Nearest integer)

[Atomic Masses - Na : 23.0 u, O : 16.0 u, P : 31.0 u]

The overall stability constant of the complex ion [Cu(NH₃)₄]²⁺ is 2.1 $$\times$$ 10¹³. The overall dissociations constant is y $$\times$$ 10^$$-$$14. Then y is __________. (Nearest integer)

83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is ____________ K. (Nearest integer)

[Use : Molal Freezing point depression constant of water = 1.86 K kg mol^$$-$$1]

Freezing Point of water = 273 K

Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u]