A cylinder containing an ideal gas (0.1 mol of 1.0 dm³) is in thermal equilibrium with a large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the stoppers S₁ and S₂ (as shown in the figure) are suddenly withdrawn, the volume of the gas in litres after equilibrium is achieved will be____.

(Given, K_f (water) = 2.0 K kg mol^–1,
R = 0.08 dm³ atm K^–1 mol^–1)

Consider the following reactions,


The compound [P] is :

The decreasing order of basicity of the following amines is :

The reaction of H₃N₃B₃Cl₃ (A) with LiBH₄ in tetrahydrofuran gives inorganic benzene (B). Further, the reaction of (A) with (C) leads to H₃N₃B₃(Me)₃. Compounds (B) and (C) respectively, are :