The electronic configuration with the highest ionization enthalpy is :

A solution is prepared by mixing 8.5 g of CH₂Cl₂ and 11.95 g of CHCl₃ . If vapour pressure of CH₂Cl₂ and CHCl₃ at 298 K are 415 and 200 mmHg respectively, the mole fraction of CHCl₃ in vapour form is : (Molar mass of Cl = 35.5 g mol⁻¹)

The rate of a reaction quadruples when the temperature changes from 300 to 310 K. The activation energy of this reaction is :

(Assume activation energy and preexponential factor are independent of temperature; ln 2 = 0.693; R = 8.314 J mol⁻¹ K⁻¹)

To find the standard potential of M³⁺/M electrode,the following cell is constituted : Pt/M/M³⁺(0.001 mol L⁻¹ )/Ag⁺(0.01 mol L⁻¹ )/Ag

The emf of the cell is found to be 0.421 volt at 298 K. The standard potential of half reaction M3⁺ + 3e⁻$$ \to $$ M at 298 K will be :

(Given $$E_{A{g^ + }\,/\,Ag}^ - $$ at 298 K = 0.80 Volt)