[Given : The density of $30 \%$ (w/v), aqueous solution of glucose is $1.2 \mathrm{~g} \mathrm{~cm}^{-3}$ and vapour pressure of pure water is $24 \mathrm{~mm}~ \mathrm{Hg}$.]

(Molar mass of glucose is $180 \mathrm{~g} \mathrm{~mol}^{-1}$.)

Sea water contains $$29.25 \% ~\mathrm{NaCl}$$ and $$19 \% ~\mathrm{MgCl}_{2}$$ by weight of solution. The normal boiling point of the sea water is _____________ $${ }^{\circ} \mathrm{C}$$ (Nearest integer)

Assume $$100 \%$$ ionization for both $$\mathrm{NaCl}$$ and $$\mathrm{MgCl}_{2}$$

Given : $$\mathrm{K}_{\mathrm{b}}\left(\mathrm{H}_{2} \mathrm{O}\right)=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$

Molar mass of $$\mathrm{NaCl}$$ and $$\mathrm{MgCl}_{2}$$ is 58.5 and 95 $$\mathrm{g} \mathrm{~mol}^{-1}$$ respectively.

Solution of $$12 \mathrm{~g}$$ of non-electrolyte (A) prepared by dissolving it in $$1000 \mathrm{~mL}$$ of water exerts the same osmotic pressure as that of $$0.05 ~\mathrm{M}$$ glucose solution at the same temperature. The empirical formula of $$\mathrm{A}$$ is $$\mathrm{CH}_{2} \mathrm{O}$$. The molecular mass of $$\mathrm{A}$$ is __________ g. (Nearest integer)

80 mole percent of $$\mathrm{MgCl}_{2}$$ is dissociated in aqueous solution. The vapour pressure of $$1.0 ~\mathrm{molal}$$ aqueous solution of $$\mathrm{MgCl}_{2}$$ at $$38^{\circ} \mathrm{C}$$ is ____________ $$\mathrm{mm} ~\mathrm{Hg.} ~\mathrm{(Nearest} ~\mathrm{integer)}$$

Given : Vapour pressure of water at $$38^{\circ} \mathrm{C}$$ is $$50 \mathrm{~mm} ~\mathrm{Hg}$$