1.22 g of an organic acid is separately dissolved in 100 g of benzene (K_b = 2.6 K kg mol^$$-$$1) and 100 g of acetone (K_b = 1.7 K kg mol^$$-$$1). The acid is known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by 0.17$$^\circ$$C. The increase in boiling point of solution in benzene in $$^\circ$$C is x $$\times$$ 10^$$-$$2. The value of x is ______________. (Nearest integer) [Atomic mass : C = 12.0, H = 1.0, O =16.0]

40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of solution is __________ K. (Nearest integer) [Given : K_f = 1.86 K kg mol^$$-$$1; Density of water = 1.00 g cm^$$-$$3; Freezing point of water = 273.15 K]

1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to $$-$$4$$^\circ$$C before freezing. The amount of ice (in g) that will be separated out is __________. (Nearest integer)

[Given : K_f(H₂O) = 1.86 K kg mol^$$-$$1]

83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is ____________ K. (Nearest integer)

[Use : Molal Freezing point depression constant of water = 1.86 K kg mol^$$-$$1]

Freezing Point of water = 273 K

Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u]