Given below are two statements :

Statement (I) : A $\pi$ bonding MO has lower electron density above and below the inter-nuclear axis.

Statement (II) : The $\pi^*$ antibonding MO has a node between the nuclei.

In the light of the above statements, choose the most appropriate answer from the options given below :

Select the compound from the following that will show intramolecular hydrogen bonding.

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): $\mathrm{PH}_3$ has lower boiling point than $\mathrm{NH}_3$.

Reason (R) : In liquid state $\mathrm{NH}_3$ molecules are associated through vander Waal's forces, but $\mathrm{PH}_3$ molecules are associated through hydrogen bonding.

In the light of the above statements, choose the most appropriate answer from the options given below :