The correct order of first ionisation enthalpy is :

Given below are two statements :

Statement I : Hyperconjugation is a permanent effect.

Statement II : Hyperconjugation in ethyl cation $$\left( {C{H_3} - \mathop C\limits^ + {H_2}} \right)$$ involves the overlapping of $${C_{s{p^2}}} - {H_{1s}}$$ bond with empty 2p orbital of other carbon.

Choose the correct option :

Given below are two statements :

Statement I : $${[Mn{(CN)_6}]^{3 - }}$$, $${[Fe{(CN)_6}]^{3 - }}$$ and $${[Co{({C_2}{O_4})_3}]^{3 - }}$$ are d²sp³ hybridised.

Statement II : $${[MnCl)_6}{]^{3 - }}$$ and $${[Fe{F_6}]^{3 - }}$$ are paramagnetic and have 4 and 5 unpaired electrons, respectively.

In the light of the above statements, choose the correct answer from the options given below :

To an aqueous solution containing ions such as Al³⁺, Zn²⁺, Ca²⁺, Fe³⁺, Ni²⁺, Ba²⁺ and Cu²⁺ was added conc. HCl, followed by H₂S.

The total number of cations precipitated during this reaction is/are :