Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R :

Assertion A : Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom.

Reason R : Phenols react with halogen acids violently.

In the light of the above statements, choose the most appropriate from the options given below :

Identify B formed in the reaction.

$$\mathrm{Cl}-\left(\mathrm{CH}_2\right)_4-\mathrm{Cl} \xrightarrow{\text { excess } \mathrm{NH}_3} \mathrm{~A} \xrightarrow{\mathrm{NaOH}} \mathrm{B}+\mathrm{H}_2 \mathrm{O}+\mathrm{NaCl}$$

Which among the following halide/s will not show $$\mathrm{S_N 1}$$ reaction:

(A) $$\mathrm{H}_2 \mathrm{C}=\mathrm{CH}-\mathrm{CH}_2 \mathrm{Cl}$$

(B) $$\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{Cl}$$

(C)

(D)

Choose the most appropriate answer from the options given below :

The correct statement regarding nucleophilic substitution reaction in a chiral alkyl halide is ;