Evaluate the following statements related to group 14 elements for their correctness.
(A) Covalent radius decreases down the group from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ in a regular manner.
(B) Electronegativity decreases from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ down the group gradually.
(C) Maximum covalance of $$\mathrm{C}$$ is 4 whereas other elements can expand their covalance due to presence of d orbitals.
(D) Heavier elements do not form $$\mathrm{p} \pi-\mathrm{p} \pi$$ bonds.
(E) Carbon can exhibit negative oxidation states.
Choose the correct answer from the options given below :
Given below are two statements :
Statement I : Gallium is used in the manufacturing of thermometers.
Statement II : A thermometer containing gallium is useful for measuring the freezing point $$(256 \mathrm{~K})$$ of brine solution.
In the light of the above statements, choose the correct answer from the options given below :
Which of the following material is not a semiconductor.
The correct statements from the following are :
(A) The decreasing order of atomic radii of group 13 elements is $$\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}>\mathrm{Al}>\mathrm{B}$$.
(B) Down the group 13 electronegativity decreases from top to bottom.
(C) $$\mathrm{Al}$$ dissolves in dil. $$\mathrm{HCl}$$ and liberates $$\mathrm{H}_2$$ but conc. $$\mathrm{HNO}_3$$ renders $$\mathrm{Al}$$ passive by forming a protective oxide layer on the surface.
(D) All elements of group 13 exhibits highly stable +1 oxidation state.
(E) Hybridisation of $$\mathrm{Al}$$ in $$[\mathrm{Al}(\mathrm{H}_2 \mathrm{O})_6]^{3+}$$ ion is $$\mathrm{sp}^3 \mathrm{d}^2$$.
Choose the correct answer from the options given below :