A 'p'-block element $(\mathrm{E})$ and hydrogen form a binary cation $\left(\mathrm{EH}_{\mathrm{x}}\right)^{+}$, while $\mathrm{EH}_3$ on treatment with $\mathrm{K}_2 \mathrm{HgI}_4$ in alkaline medium gives a precipitate of basic mercury(II)amido-iodine. Given below are first ionisation enthalpy values $\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)$ for first element each from group 13, 14, 15 and 16. Identify the correct first ionisation enthalpy value for element E.

Consider the following reactions.

$\underset{\text { (Hot solution) }}{\mathrm{PbCl}_2}+\mathrm{K}_2 \mathrm{CrO}_4 \rightarrow A+2 \mathrm{KCl}$

$$ \begin{aligned} & \mathrm{A}+\mathrm{NaOH} \rightleftharpoons \mathrm{~B}+\mathrm{Na}_2 \mathrm{CrO}_4 \\ & \mathrm{PbSO}_4+4 \mathrm{CH}_3 \mathrm{COONH}_4 \rightarrow\left(\mathrm{NH}_4\right)_2 \mathrm{SO}_4+\mathrm{X} \end{aligned} $$

In the above reactions, $\mathrm{A}, \mathrm{B}$ and X are respectively.

Given below are two statements :

Statement I : The number of pairs among $\left[\mathrm{SiO}_2, \mathrm{CO}_2\right],\left[\mathrm{SnO}, \mathrm{SnO}_2\right],\left[\mathrm{PbO}, \mathrm{PbO}_2\right]$ and $\left[\mathrm{GeO}, \mathrm{GeO}_2\right]$, which contain oxides that are both amphoteric is 2 .

Statement II : $\mathrm{BF}_3$ is an electron deficient molecule, can act as a Lewis acid, forms adduct with $\mathrm{NH}_3$ and has a trigonal planar geometry.

In the light of the above statements, choose the correct answer from the options given below :

The correct statements from the following are :

(A) Tl³⁺ is a powerful oxidising agent

(B) Al³⁺ does not get reduced easily

(C) Both Al³⁺ and Tl³⁺ are very stable in solution

(D) Tl¹⁺ is more stable than Tl³⁺

(E) Al³⁺ and Tl¹⁺ are highly stable

Choose the correct answer from the options given below :