Number of isomeric compounds with molecular formula $$\mathrm{C}_{9} \mathrm{H}_{10} \mathrm{O}$$ which (i) do not dissolve in $$\mathrm{NaOH}$$ (ii) do not dissolve in $$\mathrm{HCl}$$. (iii) do not give orange precipitate with 2,4-DNP (iv) on hydrogenation give identical compound with molecular formula $$\mathrm{C}_{9} \mathrm{H}_{12} \mathrm{O}$$ is ____________.
Number of compounds from the following which will not dissolve in cold $\mathrm{NaHCO}_{3}$ and $\mathrm{NaOH}$ solutions but will dissolve in hot $\mathrm{NaOH}$ solution is ________.
A trisubstituted compound '$$\mathrm{A}$$', $$\mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_{2}$$ gives neutral $$\mathrm{FeCl}_{3}$$ test positive. Treatment of compound 'A' with $$\mathrm{NaOH}$$ and $$\mathrm{CH}_{3} \mathrm{Br}$$ gives $$\mathrm{C}_{11} \mathrm{H}_{14} \mathrm{O}_{2}$$, with hydroiodic acid gives methyl iodide and with hot conc. $$\mathrm{NaOH}$$ gives a compound $$\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_{2}$$. Compound 'A' also decolorises alkaline $$\mathrm{KMnO}_{4}$$. The number of $$\pi$$ bond/s present in the compound '$$\mathrm{A}$$' is _____________.