Ionic radii of cation $$\mathrm{A}^{+}$$ and anion $$\mathrm{B}^{-}$$ are 102 and $$181 \,\mathrm{pm}$$ respectively. These ions are allowed to crystallize into an ionic solid. This crystal has cubic close packing for $$\mathrm{B}^{-}$$. $$\mathrm{A}^{+}$$ is present in all octahedral voids. The edge length of the unit cell of the crystal AB is __________ pm. (Nearest Integer)

Metal $$\mathrm{M}$$ crystallizes into a fcc lattice with the edge length of $$4.0 \times 10^{-8} \mathrm{~cm}$$. The atomic mass of the metal is ____________ $$\mathrm{g} / \mathrm{mol}$$. (Nearest integer)

$$\left(\right.$$ Use : $$\mathrm{N}_{\mathrm{A}}=6.02 \times 10^{23} \mathrm{~mol}^{-1}$$, density of metal, $$\mathrm{M}=9.03 \mathrm{~g} \mathrm{~cm}^{-3}$$ )

An element M crystallises in a body centred cubic unit cell with a cell edge of $$300 \,\mathrm{pm}$$. The density of the element is $$6.0 \mathrm{~g} \mathrm{~cm}^{-3}$$. The number of atoms present in $$180 \mathrm{~g}$$ of the element is ____________ $$\times 10^{23}$$. (Nearest integer)

Metal deficiency defect is shown by Fe_0.93O. In the crystal, some Fe²⁺ cations are missing and loss of positive charge is compensated by the presence of Fe³⁺ ions. The percentage of Fe²⁺ ions in the Fe_0.93O crystals is __________. (Nearest integer)