During the detection of acidic radical present in a salt, a student gets a pale yellow precipitate soluble with difficulty in $$\mathrm{NH}_4 \mathrm{OH}$$ solution when sodium carbonate extract was first acidified with dil. $$\mathrm{HNO}_3$$ and then $$\mathrm{AgNO}_3$$ solution was added. This indicates presence of :
Match List I with List II
LIST I (Precipitating reagent and conditions) |
LIST II (Cation) |
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---|---|---|---|
A. | $$ \mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH} $$ |
I. | $$\mathrm{Mn^{2+}}$$ |
B. | $$ \mathrm{NH}_4 \mathrm{OH}+\mathrm{Na}_2 \mathrm{CO}_3 $$ |
II. | $$\mathrm{Pb^{2+}}$$ |
C. | $$ \mathrm{NH}_4 \mathrm{OH}+\mathrm{NH}_4 \mathrm{Cl}+\mathrm{H}_2 \mathrm{~S} \text { gas } $$ |
III. | $$\mathrm{Al^{3+}}$$ |
D. | dilute $$\mathrm{HCl}$$ | IV. | $$\mathrm{Sr^{2+}}$$ |
Choose the correct answer from the options given below:
In the precipitation of the iron group (III) in qualitative analysis, ammonium chloride is added before adding ammonium hydroxide to :
Appearance of blood red colour, on treatment of the sodium fusion extract of an organic compound with $$\mathrm{FeSO}_4$$ in presence of concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$ indicates the presence of element/s