Consider the following reaction of benzene.

In compound $(Q)$, the percentage of oxygen is $\_\_\_\_$ %. (Nearest integer)

The cycloalkene $(\mathrm{X})$ on bromination consumes one mole of bromine per mole of $(\mathrm{X})$ and gives the product $(\mathrm{Y})$ in which $\mathrm{C}: \mathrm{Br}$ ratio is 3:1. The percentage of bromine in the product $(\mathrm{Y})$ is $\_\_\_\_$ %. (Nearest integer)

(Given : molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{O}: 16, \mathrm{Br}: 80$ )

Isomeric hydrocarbons → negative Baeyer’s test

(Molecular formula C₉H₁₂)

The total number of isomers from above with four different non-aliphatic substitution sites is -

The sum of sigma (σ) and pi (π) bonds in Hex-1,3-dien-5-yne is ________.