For a solution formed by mixing liquids $$L$$ and $$M,$$ the vapor pressure of $$L$$ plotted against the mole fraction of $$M$$ in solution is shown in the following figure. Here $${X_L}$$ and $${X_M}$$ represent mole fractions of $$L$$ and $$M,$$ respectively, in the solution. The correct statement(s) applicable to this system is (are)

Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively.

	Column 1		Column 2		Column 3
(I)	Toluene	(i)	NaOH/Br2	(P)	Condensation
(II)	Acetophenone	(ii)	Br2/hv	(Q)	Carboxylation
(III)	Benzaldehyde	(iii)	(CH3CO)2O/ CH3COOK	(R)	Substitution
(IV)	Phenol	(iv)	NaOH/CO2	(S)	Haloform

The only CORRECT combination in which the reaction proceeds through radical mechanism is :

Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively.

	Column 1		Column 2		Column 3
(I)	Toluene	(i)	NaOH/Br2	(P)	Condensation
(II)	Acetophenone	(ii)	Br2/hv	(Q)	Carboxylation
(III)	Benzaldehyde	(iii)	(CH3CO)2O/ CH3COOK	(R)	Substitution
(IV)	Phenol	(iv)	NaOH/CO2	(S)	Haloform

The only CORRECT combination that gives two different carboxylic acids is :

The wave function, $${\psi _{n,1,{m_1}}}$$ is a mathematical function whose value depends upon spherical polar coordinates $$\left( {r,\theta ,\phi } \right)$$ of the electron and characterized by the quantum numbers $$n,1$$ and $${m_1}$$. Here $$r$$ is distance from nucleus, $$\theta $$ is colatitude and $$\phi $$ is azimuth. In the mathematical functions given in the table, $$Z$$ is atomic number and $${a_0}$$ is Bohr radius.

For $$H{e^ + }$$ ion, the only INCORRECT combination is